Exploring Electrochemically Mediated ATRP of Styrene
نویسندگان
چکیده
Electrochemically mediated atom transfer radical polymerization (eATRP) of styrene was studied in detail by using CuBr2/TPMA (TPMA = tris(2-pyridylmethyl)amine) as a catalyst. Redox properties various Cu(II) species were investigated CH3CN, dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) both the absence presence 50% (v/v) styrene. This investigation together with preliminary eATRP experiments at 80 °C indicated DMF best solvent. The effects catalyst, monomer, initiator concentrations also examined. livingness chain extension electrochemical temporal control polymerization.
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ژورنال
عنوان ژورنال: Processes
سال: 2021
ISSN: ['2227-9717']
DOI: https://doi.org/10.3390/pr9081327